Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 950, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2021.121979
Keywords
Carbon dioxide; Metallophthalocyanines; Bifunctional catalysts; Polycarbonates; Cyclic carbonates
Categories
Funding
- FCT - Fundacao para a Ciencia e a Tecnologia, I.P. [UID/QUI/00313/2019, PTDC/QUI-OUT/27996/2017]
- FCT [UI/BD/150804/2020, PD/BD/143123/2019]
- Fundação para a Ciência e a Tecnologia [UI/BD/150804/2020, PD/BD/143123/2019, UID/QUI/00313/2019, PTDC/QUI-OUT/27996/2017] Funding Source: FCT
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A sustainable synthetic methodology was used to prepare bifunctional cationic imidazolyl and neutral tertbutylphenoxy Al(III)-phthalocyanine complexes, which were efficient catalysts in promoting CO2-cycloaddition reactions with epoxides. The structure of the phthalocyanine was found to determine the reaction selectivity towards cyclic carbonates versus polycarbonates, demonstrating their potential in green chemistry applications.
A sustainable synthetic methodology to prepare bifunctional cationic imidazolyl and neutral tertbutylphenoxy Al(III)-phthalocyanine complexes is described, using ultrasound irradiation to synthesize the phthalonitrile precursors, followed by microwave-assisted cyclotetramerization. The metallophthalocyanine catalysts were applied in the coupling reaction of CO2 with epoxides, where the structure of the phthalocyanine was shown to determine the reaction selectivity towards the formation of cyclic carbonates versus polycarbonates. The cationic imidazolyl phthalocyanines operate as efficient bifunctional catalysts to promote the CO2 cycloaddition to terminal epoxides (styrene oxide, epichlorohydrin, propylene oxide and allyl glycidyl ether), leading to TONs up to 1414 and 100% selectivity for cyclic carbonates, without the need of using any co-catalyst. On the other hand, the neutral 4-tert-butylphenoxy Al(III) phthalocyanine catalyzed the copolymerization reaction between CO2 and cyclohexene oxide, in the presence of PPNCl as co-catalyst, with TON = 814, providing the first example of a metallophthalocyanine catalyst with full selectivity for formation of polycarbonates. (C) 2021 Elsevier B.V. All rights reserved.
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