Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 951, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2021.122007
Keywords
Salen; Organoaluminium complex; epsilon-Caprolactone; Ring-opening polymerization; Copolymerizaton
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Funding
- National Natural Science Foundation of China [21871198, 21674070]
- PAPD
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Several aluminium alkyl and alkyloxide complexes supported by a thioether-bridged salen ligand were synthesized through the protonolysis reaction. These complexes showed higher catalytic activity for the homopolymerization of epsilon-caprolactone and the copolymerization of L-lactide and epsilon-caprolactone.
Several aluminium alkyl and alkyloxide complexes supported by a thioether-bridged salen ligand were synthesized by the protonolysis reaction. Reactions of N,N'-bis(3,5-di-tert-butylsalicylidene)-2,2'-diaminophenylsulfide (H2L) with one or two equivalents of AlMe3 in toluene at 100 degrees C afforded the corresponding mono- and binuclear aluminium methyl complexes LAlMe (1) and L(AlMe2)(2) (2). Treatment of the in situ generated complex 1 with one equivalent of ROH (R = PhCH2, iPr, CH3OCH2CH2) produced the desired aluminium alkyloxide complexes LAlOCH2Ph (3), LAl((OPr)-Pr-i) (4) and LAlO(CH2)(2)OCH3 (5). All the molecular structures were established by single crystal X-ray diffraction studies. It was found that aluminium alkyloxide complexes 3-5 showed higher catalytic activity for the homopolymerization of epsilon-caprolactone (epsilon-CL) than corresponding aluminium methyl complexes 1 and 2. Furthermore, these alkyloxide complexes were also efficient initiators for the copolymerization of L-lactide and epsilon-CL to give practically random copolymers. (C) 2021 Elsevier B.V. All rights reserved.
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