4.7 Article

Synthesis of Conjugated Donor-Acceptor Antiaromatic Porphyrins and Their Application to Perovskite Solar Cells

Journal

JOURNAL OF ORGANIC CHEMISTRY
Volume 87, Issue 9, Pages 5457-5463

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.1c01947

Keywords

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Funding

  1. University of Science and Technology of China [KY234000006]
  2. SICORP of the Japan Science and Technology Agency (JST) [JPMJSC18H1]
  3. CREST of the Japan Science and Technology Agency (JST) [JPMJCR20B5]
  4. Japan Society for the Promotion of Science (JSPS) [JP20H00220, JP21K18956]

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A conjugated donor-acceptor antiaromatic porphyrin was synthesized and successfully applied in a perovskite solar cell, leading to a significantly increased power conversion efficiency.
A conjugated donor-acceptor antiaromatic porphyrin, composed of an antiaromatic thieno-fused porphyrin structure and a diketopyrrolopyrrole mioety, was synthesized and applied in a perovskite solar cell for the first time. Enhanced light absorption in the device by the antiaromatic porphyrin resulted in a significantly increased power conversion efficiency of 19.3%.

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