Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 87, Issue 2, Pages 1457-1469Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.1c02776
Keywords
-
Categories
Funding
- Swedish Research Council FORMAS [2019-00699]
- Olle Engkvists Stiftelse
- Formas [2019-00699] Funding Source: Formas
Ask authors/readers for more resources
This paper reports a catalytic electron donor-acceptor (EDA) complex for visible light-driven annulation reaction between alkylated alkenes and N,N-substituted dialkyl anilines. Investigations into the mechanism reveal the rare example of a catalytic acceptor in photoactive EDA complexes that can give selective functionalization of aromatic amines under mild photochemical conditions.
A catalytic electron donor-acceptor (EDA) complex for the visible-light-driven annulation reaction between activated alkenes and N,N-substituted dialkyl anilines is reported. The key photoactive complex is formed in situ between dialkylated anilines as donors and 1,2-dibenzoylethylene as a catalytic acceptor. The catalytic acceptor is regenerated by aerobic oxidation. Investigations into the mechanism are provided, revealing a rare example of a catalytic acceptor in photoactive EDA complexes that can give access to selective functionalization of aromatic amines under mild photochemical conditions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available