Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 87, Issue 1, Pages 547-555Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.1c02559
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Funding
- NSF of China [U2004192]
- Program for Science and Technology Innovation Talents in University of Henan Province [21HASTTT005]
- Science and Technology Research Project of Henan Province [202102310331]
- Key Scientific Research Project of Higher Education of Henan Province [19A150004]
- Nanyang Normal University [2019ZX006, 2018ZX001]
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A new method was developed to construct cyclic phosphinamides with various functional groups under mild conditions via an intramolecular electrochemical C-H phosphinamidation process. This method also provided an alternative route to organic electroluminescent materials and P-N ligands.
We developed an oxidant- and transition-metal-free approach to construct six-membered cyclic phosphinamides via an intramolecular electrochemical C-H phosphinamidation process. With (Bu4NBr)-Bu-n as the catalyst and electrolyte, cyclic phosphinamides bearing a variety of functional groups (22 examples) were readily accessed under mild conditions. Meanwhile, this protocol provided an alternative route to organic electroluminescent materials and P-N ligands.
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