Journal
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
Volume 88, Issue 5, Pages 633-643Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20150081
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The concept and representative examples of element-block polymers are described. A structural unit consisting of various groups of elements is called an element-block. In this review, unique properties of element-block polymers composed of organoboron complexes, o-carboranes, and polyhedral oligomeric silsesquioxanes as typical examples of element blocks are illustrated. The design and synthesis of new element-blocks and development of methods forming higher-order structures for realizing the desired functions based on a bottom-up approach are explained.
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