4.4 Article

A novel Ag nanoparticles purification method and the conductive ink based on the purified Ag nanoparticles for printed electronics

Journal

JOURNAL OF NANOPARTICLE RESEARCH
Volume 24, Issue 1, Pages -

Publisher

SPRINGER
DOI: 10.1007/s11051-022-05401-x

Keywords

Ag; Purification; Membrane; Nanoscale; X-ray diffraction (XRD); Transmission electron microscopy (TEM); Colloids

Funding

  1. Key Program of Science and Technology in Hunan [2018GK4015]

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In this study, a novel method called membrane separation-centrifugation technology was used to purify AgNPs. The results showed that the cleaned AgNPs obtained through this method had minimal organic residues, were pure single-crystal cubic phase Ag, and had nanoscale size and excellent stability. Furthermore, the AgNPs ink made from these purified AgNPs exhibited low electrical resistivity. These findings highlight the significance of this study in the field of printed electronics.
In this study, a novel method called membrane separation-centrifugation technology is used to purify the AgNPs. The TGA results showed that the AgNPs washed in this method only contained a minimal amount of organic residues (<5 wt.%). Moreover, the XRD results indicate that the cleaned AgNPs are pure single-crystal cubic phase Ag without other impurities. Furthermore, according to the results of SEM and TEM, the AgNPs cleaned by this technology are nanoscale with an average particle size of only 50 nm and dispersed evenly without agglomeration. The colloid made from AgNPs purified by this method reveals a good Zeta potential of about -34.7 mV, which indicates the excellent stability of AgNPs. After the ink made by these AgNPs is dried at 150 degrees C for 10 min, a really low electrical resistivity only about 10.7 x 10(-6) Omega.cm is obtained. These results confirm that the membrane separation-centrifugation technology can significantly improve the performances of the AgNPs ink, which can be used in printed electronics.

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