Journal
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
Volume 88, Issue 9, Pages 1201-1220Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20150130
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Funding
- Ministry of Education, Culture, Sports, Science and Technology of Japan [19002008]
- Scientific Research on Innovative Areas, Stimuli-responsive Chemical Species for the Creation of Functional Molecules [2408, 24109003]
- [24350031]
- [15H03788]
- Grants-in-Aid for Scientific Research [15H03788, 26620051, 24109003] Funding Source: KAKEN
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Kinetic stabilization with sterically bulky substituents or ligands has played a pivotal role in exploring a large variety of unsaturated compounds or low-coordinated complexes. This article describes our findings that a series of fused-ring octa-R-substituted s-hydrindacenyl groups (Rind groups), which we developed since 2007, can act as unique protecting groups both in main group chemistry and in transition-metal chemistry. The synthesis, structures, and properties of various types of highly reactive unsaturated and low-coordinated element-organic compounds of Groups 1, 2, 8, 11, and 13-17 featuring the bulky Rind groups are covered.
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