4.4 Article

Synthesis and Properties of Extended π-Conjugated Compounds with 9,10-Bis(phenylethynyl)anthracene Units

Journal

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
Volume 88, Issue 1, Pages 192-199

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20140279

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Funding

  1. MEXT KAKENHI [24106743]
  2. JSPS KAKENHI [26410060]
  3. MEXT
  4. Grants-in-Aid for Scientific Research [26410060] Funding Source: KAKEN

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New extended pi-conjugated compounds with two 9,10-bis(phenylethynyl)anthracene units and various linkers were synthesized by one-shot double-elimination reactions and Sonogashira coupling. Their UV-vis and fluorescence spectra were measured to evaluate the effects of the linkers on the pi-conjugation. Their photophysical properties are discussed in terms of structures and molecular orbitals obtained by DFT calculations.

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