Journal
JOURNAL OF MOLECULAR STRUCTURE
Volume 1250, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.molstruc.2021.131698
Keywords
Pyrrolidinyl chalcones; Energy band gaps; Functional groups; ASE
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Funding
- National Plan for Science, Technology, and innovation (MAARIFAH)-King Abdulaziz City for Science and Technology-the Kingdom of Saudi Arabia [14-ADV989-08]
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This study investigates the synthesis, structural features, and spectral properties of novel chalcone derivatives. The energy band gaps of these chalcones can be significantly lowered by adding electron-donating groups, while electron-withdrawing groups have the opposite effect. The substitution of functional groups can red-shift the ASE spectra to longer wavelengths.
This work demonstrates the synthesis, structural features, and spectral properties of novel 3-(4(pyrrolidinyl) phenyl)-1-(4,3 di-substituted phenyl)-(2E)-propen-1-one chalcone derivatives. Their absorption, fluorescence, NMR spectra, influence of functional groups, energy band gaps, Stokes shift, and amplified spontaneous emission (ASE) are thoroughly studied. The band gaps of these chalcones are significantly lowered by adding electron-donating groups. In contrast, the electron-withdrawing groups lead to decreasing the energy band gap value. When the pyrrolidinyl group is replaced with N, N-dimethylamino group, the energy gap value decreases. The effect of functional groups (altering the pyrrolidinyl by N, N dimethylamino) red-shifts the ASE spectra to longer wavelengths. Under a suitable pump power energy excitation and concentration, these chalcones exhibit a wide range of ASE spectra. (c) 2021 Elsevier B.V. All rights reserved.
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