Unlocking bulk and surface oxygen transport properties of mixed oxide-ion and electron conducting membranes with combined oxygen permeation cell and oxygen probe method

Surface exchange kinetics and bulk diffusion of oxygen are of paramount importance to the activity of oxygen electrocatalysis and performance of electrochemical devices such as fuel cell, metal-air batteries, and oxygen separation membranes. Conventional approaches to obtaining these transport properties are often limited to single property under a specific non-operation related condition. Here we use a combined oxygen permeation cell and oxygen probe methodology to simultaneously attain rates of oxygen surface exchange and bulk conductivity/chemical diffusivity of three representative mixed oxide-ion and electron conductors, namely SrCo0.9Ta0.1O3-delta (SCT), La0.6Sr0.4CoO3-delta (LSC) and La0.6Sr0.4FeO3-delta (LSF), operated under a steady-state oxygen flux. The results explicitly show that SCT exhibit the highest oxide-ion conductivity/chemical diffusivity, fastest rates of surface oxygen exchange kinetics, thus promising to be the best oxygen electrocatalyst. We have also mapped out the distribution of oxygen chemical potential gradient across the membranes and applied B-transport number concept to illustrate the rate-limiting steps in the overall oxygen permeation process.

Automated summary

Surface exchange kinetics and bulk diffusion of oxygen are crucial for the performance of oxygen electrocatalysis and electrochemical devices. In this study, oxygen surface exchange rates and bulk conductivity/chemical diffusivity were measured for three mixed oxide-ion and electron conductors. The results showed that one of the conductors exhibited the best oxygen electrocatalytic performance.