Journal
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
Volume 88, Issue 1, Pages 146-148Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20140250
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Funding
- Grants-in-Aid for Scientific Research [24510298, 24550055, 26410121, 15K05429] Funding Source: KAKEN
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Construction of macrocyclic trienes by diene-ene RCM of tetraenes was examined. In the reactions, macrocyclic trienes were obtained as a mixture of two isomers with E,Z-configured 1,3-diene moiety. The formation of two isomers can be understandable by the E-Z isomerization of the initially generated ruthenium alkenyl carbene intermediate.
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