4.5 Article

The Dielectric Properties and Thermal Conductivities of Epoxy Composites Reinforced by Titanium Dioxide

Journal

Publisher

SPRINGER
DOI: 10.1007/s10904-021-02159-y

Keywords

Thermal conductivity; Dielectric constant; Dielectric loss; TiO2; Epoxy

Funding

  1. Natural Science Research Program of Shaanxi Province [2021JQ-798]
  2. Scientific Research Program of Education Department of Shaanxi Province [21JK0870]
  3. Xian Association for Science and Technology Young Talent Promotion Project [095920211335]
  4. Environmental Pollution Monitoring and Control Innovation Team of Education Department of Shaanxi Province [51]
  5. Xi'an University [XAWLKYTD018]

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S-TiO2 with microspheres structure was prepared via hydrothermal process and used as a modifier in EP resin to improve dielectric properties and thermal conductivities of S-TiO2/EP composites. The reasonable content of S-TiO2 enhanced the dielectric constant without excessive increase in dielectric loss, while also improving the thermal conductivity of the composites.
To improve the dielectric properties and thermal conductivities of epoxy resins (EP), titanium dioxide superfine powders with microspheres structure (S-TiO2) were prepared via a hydrothermal process based on the sodium dodecyl benzene sulfonate and hydroxyl silicate. The different content of S-TiO2 was then employed as modifiers to add into EP resin to prepare the S-TiO2/EP composites. The structure and morphology of the prepared S-TiO2 was observed by X-ray diffraction (XRD) and scanning electron microscopy (SEM), and influences of different addition of S-TiO2 on the thermal conductivity of S-TiO2/EP composites are researched, while their dielectric constant and dielectric loss are also studied. The results suggested that the reasonable content of S-TiO2 can endow the S-TiO2/EP composites with higher dielectric constant without excessive increase their dielectric loss even under the high frequency. Furthermore, the thermal conductivity of S-TiO2/EP are also be improved, which can be attributed to the good thermal conductivity of S-TiO2 itself and the thermal conductivity path formed by S-TiO2 inside the EP matrix.

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