4.7 Article

Spin polarization and magneto-dielectric coupling in Al-modified thin iron oxide films -microwave mediated sol-gel approach

Journal

JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
Volume 103, Issue -, Pages 49-66

Publisher

ELSEVIER SCIENCE INC
DOI: 10.1016/j.jiec.2021.06.028

Keywords

Thin film; Iron oxide; Aluminum; Sol-gel; Microwaves; Magneto-dielectric coupling

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A novel approach combining microwave radiations and aluminum doping is proposed to achieve multifunctionality and spin polarization in iron oxide thin films. Control over structural transitions in the thin films is achieved through the combined effect of microwave radiations and Al doping. The transition from gamma-Fe2O3 to Fe3O4 thin films is confirmed at Al concentrations of 6-10 wt%, leading to an increase in saturation magnetization and observation of Verwey transition.
Production of single-phase materials with multifunctional properties is still a challenge faced by material scientists. In addition, obtaining high spin polarization efficiency in the materials that exhibit multifunctional properties is a big issue. A novel approach is suggested in this work for obtaining multifunctionality and spin polarization in the same material. This approach has combined the effect of microwave radiations and aluminum (Al) doping in iron oxide thin films during synthesis. Combined effect of microwave radiations and Al doping results in controlling / tuning the structural transitions in iron oxide thin films. Pristine and 2-10 wt% Al doped iron oxide thin films are prepared and studied in detail. Raman analysis shows that 2 and 4 wt% Al concentration results in gamma-Fe2O3 + Fe3O4 phase with 71.3% and 64.5% of gamma-Fe2O3 content, respectively. XRD and Raman analyses confirm the transition from gamma-Fe2O3 to Fe3O4 thin films at Al concentrations of 6-10 wt%. Structural transformation shows that microwave radiations catalyzes that Al3+ ions to occupy the vacancies on B sites of iron oxide thus, lead to the formation of Fe3O4. Observation of Verwey transition similar to 126 K also supports the transition in phases of iron oxide with increase in saturation magnetization from 251.3emu/cm(3) (pristine films) to 405.6emu/cm(3) (8 wt% Al concentration). High dielectric constant of similar to 135.5 (log f = 5.0) is observed for 8 wt% Al concentration. Conductivity and detailed impedance & modulus analyses depict Mott's hopping phenomenon along with presence of different relaxation times. Coupling between magnetic and dielectric properties is observed at room temperature. Magnetoresistance curves indicate spin polarization efficiency of similar to 24%. (C) 2021 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

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