4.7 Review

Review on metal dissolution characteristics and harmful metals recovery from electronic wastes by supercritical water

Journal

JOURNAL OF HAZARDOUS MATERIALS
Volume 424, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.jhazmat.2021.127693

Keywords

Supercritical water; Salt solubility; Inorganic metal compounds; Organic metal compounds; Metal recovery

Funding

  1. National Natural Science Foundation of China [52076071]
  2. Changsha Municipal Natural Science Foundation [kq2007031]
  3. Key Projects of Hunan Province Science and Technology Plan [2018SK2019]

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Supercritical water (SCW) technology can efficiently recover toxic or complex chemical wastes, but salt deposition and corrosion hinder its commercial applications. Research on salt solubility in high pressure/temperature water provides ideas and references for follow-up research on metal recovery.
Supercritical water (SCW) technology can be applied as an efficient and environment-friendly method to recover toxic or complex chemical wastes. Separation and chemical reactions under supercritical conditions may be realized by changing the temperature, pressure, and other operating parameters to adjust the physical and chemical properties of water. However, salt deposition and corrosion are often encountered during the treatment of inorganic substances, which will hinder the commercial applications of SCW technology. The solubility of salt in high pressure/temperature water forms the theoretical basis for studying the recovery of metal salts in supercritical water and understanding salt deposition. Therefore, this work systematically and objectively reviews different research methods used to analyze salt solubility in high pressure/temperature water, including the experimental method, prediction theoretical modeling, and computer simulation method; the research status and existing data of this parameter are also analyzed. The purpose of this review is to provide ideas and references for follow-up research by providing a comprehensive overview of salt solubility research methods and the current situation. Suggestions for more efficient metal recovery through technology integration are also provided.

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