Journal
JOURNAL OF HAZARDOUS MATERIALS
Volume 421, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.jhazmat.2021.126702
Keywords
Hierarchical Porous COFs Foams; Template-assisted Synthesis; Sulfamerazine; Adsorption; Wastewater remediation
Categories
Funding
- National Natural Science Foundation of China [21806148]
- Natural Science Foundation of Zhejiang Province [LY21B070009]
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The study proposed a simple and cost-efficient strategy for the synthesis of HP-COFs, utilizing recyclable catalyst and template to produce a material with self-floating ability, which showed high efficiency in removing SMR from aqueous solution. The adsorption capacity was high and stable, and the adsorption mechanism was elucidated using DFT method.
The preparation of hierarchical porous covalent organic frameworks (HP-COFs) is of great significance due to their inherent porosity and low density. However, it is still very challenging owing to the poor machinability of COFs. Herein, a simple and cost-efficient strategy for the synthesis of HP-COFs was proposed. In particular, p-toluenesulfonic acid and NaCl, both of which can be recycled, are utilized as catalyst and template, respectively. The resulting HP-TpBD-900 featuring abundant macropore and mesopore as well as large specific surface area (similar to 700 m(2) g(-1)) possessed self-floating ability and was turned out to be a promising adsorbent for the efficient removal of sulfamerazine (SMR) in aqueous solution. The maximum adsorption capacity is 168 mg g(-1), which is more than twice in comparison to that of material prepared without NaCl template. In addition, no significant decrease in adsorption capacity was observed after 5 cycles. Furthermore, the density functional theory (DFT) method was utilized to elucidate the adsorption mechanism, which could be dominated by hydrogen bonding and C-H center dot center dot center dot pi interaction. This work not only provides a new strategy for the synthesis of HP-COFs, but also contributes to boosting the application of COFs in the field of wastewater treatment.
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