Journal
JOURNAL OF FLUORINE CHEMISTRY
Volume 250, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2021.109882
Keywords
Fluorinated; Tetralin; Fluorene; Fluoranthene; Antimony pentafluoride; X-ray structure; NMR spectroscopy
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Research shows that the reaction of perfluorotetralin with various fluorinated benzenes can lead to the formation of different perfluorinated compounds, including perfluoro-1,2,3,10b-tetrahydrofluoranthene, perfluoro-5,6-dihydrofluoranthen-6a(4H)-ol, and others.
Interaction of perfluorotetralin with 1,2,3,4-tetrafluorobenzene (1 mol) in the presence of SbF5 at 50-55 degrees C gives, after treatment of the reaction mixture with HF-pyridine, perfluoro-1,2,3,10b-tetrahydrofluoranthene. When the reaction mixture was treated with water, perfluoro-5,6-dihydrofluoranthen-6a(4H)-ol was obtained. The reaction of perfluorotetralin with 2 moles of 1,2,3,4-tetrafluorobenzene leads, after treatment with H2O, to a mixture of perfluorinated 5,6-dihydrofluoranthen-6a(4H)-ol, 8,13-dihydro-7bH-8,13-methanobenzo[5,6]cyclohepta[1,2,3-jk]fluoren-7b-ol and 13-(2,3,4,5-tetrafluorophenyl)-perfluoro-8,13-dihydro-7bH-8,13-methanobenzo[5,6]cyclohepta[1,2,3-jk]fluoren-7b-ol. When 1-(2,3,4,5-tetrafluorophenyl)perfluorotetralin was dissolved in SbF5-SO2ClF, 1-(2,3,4,5-tetrafluorophenyl)perfluoro-1-tetralinyl cation was generated. The latter undergoes cyclization at ambient temperature to form perfluoro-1,2,3,10b-tetrahydrofluoranthen-10b-yl cation, which was also generated from perfluoro-1,2,3,10b-tetrahydrofluoranthene in a separate experiment.
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