4.5 Article

Extended Gate Field Effect Transistor-Based N-Type Gallium Nitride as a pH Sensor

Journal

JOURNAL OF ELECTRONIC MATERIALS
Volume 50, Issue 12, Pages 7071-7077

Publisher

SPRINGER
DOI: 10.1007/s11664-021-09210-1

Keywords

Gallium nitride; pH sensor; EGFET; sensitivity; hysteresis

Funding

  1. RCMO (USM) [304/PFIZIK/6315514]
  2. School of Physics (USM)

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The study investigated the sensing characteristics of undoped N-type GaN-based extended gate field effect transistor (EGFET) as a pH sensor, demonstrating good sensitivity and linearity. Unique current-voltage (I-V) characteristics with gate controllability were observed in the solution. Using six buffer solutions with a pH range of 2-12, the experiment showed a reference voltage sensitivity of 24.72 mV/pH.
The exceptional properties of gallium nitride (GaN) such as distinctive band gap and strong chemical stability make it promising as a semiconductor material to detect and select ions, liquids and gases. Sensing characteristics of an extended gate field effect transistor (EGFET)-based undoped N-type GaN as a pH sensor was investigated by using six buffer solutions with pH range 2-12 at room temperature. Distinctive current-voltage (I-V) characteristics of EGFET with gate controllability were observed in a solution. The surface potential of the membrane at the sensing area is controlled by Ag/AgCl reference electrode via aqueous solution. The sensitivity in terms of reference voltage in the linear region was 24.72 mV/pH with a good linearity. There is another function in the saturation region in the expression via drain-source current (I-DS), and the outputs indicated that to 0.39 (mu A)(1/2)/pH. I-DS sensitivity proved to be a reliable outcome as a linear response along the pH range. As an indicator of the stability and the reversibility of our sensor, we measured the hysteresis with two loops. The results showed a low value of hysteresis depth of 14.98 mV and 13.06 mV for the acidic side, 30.91 and 32.72 for the basic side.

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