4.4 Article

Reduction of dislocation density in Al0.6Ga0.4N film grown on sapphire substrates using annealed sputtered AlN templates and its effect on UV-B laser diodes

Journal

JOURNAL OF CRYSTAL GROWTH
Volume 575, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.jcrysgro.2021.126325

Keywords

Laser diode; Nitrides; Metalorganic vapor phase epitaxy; Defects

Funding

  1. MEXT Private University Research Branding Project (2016-2020)
  2. JSPS KAKENHI [17H01055, 16H06415, 16H06416]
  3. JST A-step [JPMJTR201D]
  4. JST CREST [16815710]
  5. Grants-in-Aid for Scientific Research [16H06415] Funding Source: KAKEN

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In the growth of Al0.6Ga0.4N, the formation of loop dislocations during three-dimensional growth reduces the dislocation density effectively. The study found that the spontaneous nucleation behavior of Al0.6Ga0.4N strongly depends on the fabrication temperature of homo-AlN, leading to successful reduction of dislocation density to as low as 5.8 x 10(8) cm(-2).
By growing Al0.6Ga0.4N onto a sapphire substrate using an annealed sputtered AlN (SP-AlN), spontaneous three-dimensional (3D) growth of AlGaN occurs depending on the fabrication conditions. This 3D growth results in threading dislocations, which originate from misfit dislocations, forming at the heterojunction interface between AlN and AlGaN. These dislocations are found to bend and form loops between each other, thus reducing the number of dislocations propagating to the top of the AlGaN. In this study, the dependence of the growth tem-perature of a homoepitaxial AlN layer (homo-AlN) grown via metalorganic vapor phase epitaxy on SP-AlN was investigated. It was found that the spontaneous nucleation behavior of Al0.6Ga0.4N strongly depends on the fabrication temperature of homo-AlN. The results also suggest that the dominant factor behind this dependence is the increase or decrease in hillock density originated from the SP-AlN-induced screw and mixed dislocations. As a result, a dislocation density as low as 5.8 x 10(8) cm(-2) was successfully obtained for Al0.6Ga0.4N. Furthermore, the low dislocation density was compared with that of an ultraviolet (UV)-B laser diode. In a UV-B laser diode with an oscillation wavelength of 298 nm, the threshold current density required for laser oscillation was found to be reduced by roughly 30% by reducing the AlGaN dislocation density from 8.0 x 10(8) to 5.8 x 10(8) cm(-2).

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