Dual-stimuli-responsive CuS-based micromotors for efficient photo-Fenton degradation of antibiotics

Antibiotics as emerging pollutants in water pose great risks to human health. Due to their persistence in the environment, advanced oxidation processes (AOPs) have been proposed for the degradation of antibiotics. Therefore, developing efficient catalysts for AOPs becomes critical for the removal of antibiotics. Herein, we develop self-propelled CuS-based micromotors (CuS@Fe3O4/Pt) as active heterogenous catalysts for efficient photo-Fenton degradation of antibiotics. Combining the merits of conventional heterogenous and homogenous catalysts, the prepared micromotors are easy to recycle and free of secondary pollution risks, while demonstrating high degradation efficiency due to self-induced intensification of mass transfer via autonomous motion and microbubble generation. The H2O2 in the Fenton reagents can serve as the fuel for the micromotors to drive their self-propulsion by bubbles generated from catalytic decomposition of H2O2 by the platinum layer. The dual-stimuli-responsiveness of the micromotors to magnetic field and light irradiation allows multi-modes of propulsion and guidance in different systems. The efficient photothermal effect of CuS enables the micromotors to achieve collective phototactic motion toward light, whereas magnetic responsiveness facilitates the recovery and collection of the micromotors. The synergistic effect of CuS and Fe3O4 NPs in H2O2 under visible light irradiation generates a large amount of OH center dot and center dot O-2(-) to effectively degrade tetracycline within several minutes. With these advantages, the dual-stimuli-responsive CuS-based micromotors provide a new strategy for enhanced degradation of antibiotics in water purification applications. (C) 2021 Elsevier Inc. All rights reserved.

Automated summary

Self-propelled CuS-based micromotors have been developed as active heterogeneous catalysts for efficient photo-Fenton degradation of antibiotics, offering advantages such as easy recycling, absence of secondary pollution risks, and high degradation efficiency. These micromotors achieve efficient degradation through self-induced intensification of mass transfer and microbubble generation, while their dual-stimuli-responsiveness allows for multiple propulsion and guidance modes in different systems. Efficient photothermal effect of CuS enables collective phototactic motion toward light, while magnetic responsiveness facilitates recovery and collection of micromotors.