4.7 Article

Magnetic modulation of core@shell MoS2-based flower-like multicomponent nanocomposites to improve microwave attenuation

Journal

JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 608, Issue -, Pages 2387-2398

Publisher

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2021.10.138

Keywords

Magnetic modulation; Interface polarization; CoFe@MoO2; MoS2 flower-like; nanocomposites

Funding

  1. Fund of Fok Ying Tung Education Foundation
  2. Major Research Project of innovative Group of Guizhou province [2018-013]
  3. National Science Foundation of China [11474151, 11964006]
  4. Foundation of the National Key Project for Basic Research [2012CB932304]

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This study focused on the application of three-dimensional flower-like nanocomposites as microwave absorbers. By using a magnetic modulation strategy, the electromagnetic wave absorption performance of the nanocomposites was further improved. The experimental results showed that the magnetic properties and morphology of the materials were well maintained during the hydrothermal treatment/hydrogen reduction process.
Nanocomposites with a three-dimensional (3D) flower-like geometrical morphology were considered as excellent microwave absorbers (MAs) because of the numerous effective sites for the multiple reflections of electromagnetic (EM) wave. Herein, for optimizing the EM matching characteristic and taking full advantage of interface polarization, a strategy of magnetic modulation was proposed to further improve the EM wave absorption performances (EMWAPs) of MoS2-based nanocomposites. We adopted a simple hydrothermal route and a combined method of hydrothermal treatment/hydrogen reduction to synthesize core@shell CoFe2O4@MoS2 and CoFe@MoO2/MoS2 flower-like nanocomposites, respectively. The obtained results indicated that the hydrogen reduction effectively improved their magnetic properties and magnetic loss capabilities, and their 3D flower-like geometrical morphologies were well maintained during the hydrogen reduction process. The obtained core@shell CoFe@MoO2/MoS2 flower-like

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