Journal
JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 608, Issue -, Pages 711-719Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2021.09.136
Keywords
Cobalt selenide (CoSe2); Asymmetric supercapacitors (ASCs); Energy density; Nanowires; Metal chalcogenides
Categories
Funding
- National Research Foundation of Korea [5199990414388] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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A hierarchical cobalt selenide nanowire array was designed to serve as the positive electrode for asymmetric supercapacitors, offering enhanced electrical conductivity and short ion diffusion. The obtained cobalt selenide nanowire electrode demonstrated outstanding electrochemical features with high-rate performance and stability. Additionally, an iron titanium nitride@nitrogendoped graphene was prepared as the negative electrode, resulting in an energy density of 91.8 W h kg(-1) and capacity retention of 94.6% over 10,000 cycles for the asymmetric supercapacitors. These results provide an efficient strategy for developing redox-ambitious active materials with high capacity for advanced energy-storage systems.
Transition metal selenides (TMS) have excellent research prospects and significant attention in supercapacitors (SCs) owing to their high electrical conductivity, superior electrochemical activity and excellent structural stability. However, the commercial utilization of TMS remains challenge due to their elaborate synthesis. Present study designed a hierarchical cobalt selenide (CoSe2) nanowire array on Ni-foam to serve as a positive electrode for asymmetric SCs (ASCs). The nanowires-like morphology of CoSe2 was highly advantageous for SCs, as it offered enhanced electrical conductivity, plenty of surface sites, and short ion diffusion. The as-obtained, CoSe2 nanowire electrode demonstrated outstanding electrochemical features, with an areal capacity of 1.08 mAh cm(-2) at 3 mA cm(-2), high-rate performance (69.5 % at 50 mA cm(-2)), as well as outstanding stability after 10,000 cycles. The iron titanium nitride@nitrogendoped graphene (Fe-TiN@NG) was prepared as a negative electrode to construct the ASCs cell. The obtained ASCs cell illustrated an energy density of 91.8 W h kg(-1) at a power density of 281.4 W kg(-1) and capacity retention of 94.6% over 10,000 cycles. The overall results provide a more efficient strategy to develop redox-ambitious active materials with a high capacity for advanced energy-storage systems. (C) 2021 Elsevier Inc. All rights reserved.
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