CoS2-TiO2@C Core-Shell fibers as cathode host material for High-Performance Lithium-Sulfur batteries

Owing to the low cost, high energy density, and high theoretical specific capacity, lithium-sulfur batteries have been deemed as a potential choice for future energy storage devices. However, they also have suf-fered from several scientific and technical issues including low conductivity, polysulfides migration, and volume changes. In this study, CoS2-TiO2@carbon core-shell fibers were fabricated through combination of coaxial electrospinning and selective vulcanization method. The core-shell fibers are able to efficiently host sulfur, confine polysulfides, and accelerate intermediates conversion. This electrode delivers an ini-tial specific capacity of 1181.1 mAh g(-1) and a high capacity of 736.5 mAh g(-1) after 300 cycles with high coulombic efficiency over 99.5% (capacity decay of 0.06% per cycle). This strategy of isolating interactant and selective vulcanization provides new ideas for effectively constructing heterostructure materials for lithium-sulfur batteries. (c) 2021 Elsevier Inc. All rights reserved.

Automated summary

This study analyzes the challenges of lithium-sulfur batteries and proposes a method of using core-shell fibers to construct electrodes, which effectively improves the performance of the battery, including initial specific capacity and cycling stability.