4.7 Article

Enhanced visible-light-driven photocatalytic activity of bismuth oxide via the decoration of titanium carbide quantum dots

Journal

JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 600, Issue -, Pages 161-173

Publisher

ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2021.05.022

Keywords

Ti3C2 MXene quantum dots; Bi2O3; Photocatalysis; Co-catalysis

Funding

  1. Program of National Natural Science Foundation of China [51779090, 51879101, 51579098, 51709101, 51521006, 51809090, 51909084]
  2. National Program for Support of Top-Notch Young Professionals of China (2014)
  3. Program for Changjiang Scholars and Innovative Research Team in University [IRT-13R17]
  4. Hunan Natural Science Foundation [2020JJ3009]
  5. Hunan Researcher Award Program [2020RC3025]
  6. Fundamental Research Funds for the Central Universities [531119200086, 531118010114, 531118040083, 541109060031]

Ask authors/readers for more resources

Ti3C2 QDs enhance the light response and electron transfer of Bi2O3, greatly boosting the photocatalytic performance, with the composite material showing significantly improved degradation performance for TC under visible light. Additionally, Ti3C2 QDs possess larger specific area and more active edge atoms, contributing to their key role in stimulating the photocatalytic activity of Bi2O3.
In Ti3C2 quantum dots (Ti3C2 QDs)/Bi2O3 photocatalysts system, Ti3C2 QDs can act as a co-catalyst to greatly boost the photocatalytic performance of Bi2O3. Ti3C2 QDs with excellent light adsorption ability can improve the light response of the system, and the fascinating electronic property can function as a channel for electron transfer. Moreover, Ti3C2 QDs possess larger specific area and more active edge atoms thanks to the size effect. The best Ti3C2 QDs/Bi2O3 composite with the loading amounts of 75 mL of Ti3C2 QDs solution showed much higher photocatalytic performance (nearly 5.85 times) for tetracycline (TC) degradation than that of pristine Bi2O3 under visible light irradiation. These different photocatalytic performances shed light on the key role of Ti3C2 QDs in stimulating the photocatalytic activity of Bi2O3. Moreover, Ti3C2 QDs/Bi2O3 composites exhibited excellent stability in recycling experiments and actual water sample treatment. (C) 2021 Elsevier Inc. All rights reserved.

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