4.7 Article

Gasification versus fast pyrolysis bio-oil production: A life cycle assessment

Journal

JOURNAL OF CLEANER PRODUCTION
Volume 336, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2022.130373

Keywords

Life cycle assessment; Gasification-FT; Fast pyrolysis; Agricultural waste biomass; GWP; Aspen Plus (R)

Funding

  1. 2019 Leonardo Grant for Researchers and Cultural Creators, BBVA Foundation (Spain)
  2. government of Castilla -La Mancha (Spain) [SBPLY/17/180501/000238]

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This study compares the sustainability of gasification and fast pyrolysis processes for producing bio-oil using agricultural wastes through a life cycle assessment. The findings indicate that gasification has a greater environmental impact than fast pyrolysis for all studied agricultural biomasses. The study also reveals that fast pyrolysis is the most environmentally friendly option for producing 1 MJ bio-oil.
A life cycle assessment was performed to compare the sustainability of gasification and fast pyrolysis processes for producing bio-oil using agricultural wastes from biomass. The objective was to carry out the environmental analysis associated with the production of 1 MJ bio-oil using different agricultural wastes biomasses for both thermochemical processes to determine which process is more respectful with the environment. The life cycle assessment revealed that gasification was more detrimental to the environment for all agricultural biomasses under study. In addition, greenhouse gas emissions over a 100-year time horizon were calculated, thereby demonstrating that CO2 yield emissions were higher than those for CH4 and N2O in both thermochemical processes. Furthermore, to gain a comprehensive overview, both thermochemical processes were divided into different equipment blocks to evaluate their individual impacts. Almond shell, pistachio shell and olive stone were identified as the biomasses for which minor amount of feed was needed to produce 1 MJ bio-oil. This assessment determined that the gasification stage of the gasification process and the separation stage for fast pyrolysis, were the main contributors to all mid-point impact categories. Finally, fast pyrolysis was the most environmentally friendly option for producing 1 MJ bio-oil.

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