4.7 Article

Bio-oil from biomass fast pyrolysis: Yields, related properties and energy consumption analysis of the pyrolysis system

Journal

JOURNAL OF CLEANER PRODUCTION
Volume 328, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.jclepro.2021.129613

Keywords

Almeida; Fast pyrolysis; Bio-oil; Fluidized bed; Energy consumption analysis; Rice husk; Net energy

Funding

  1. National Natural Science Foundation of China [52006200]
  2. Foundation of State Key Laboratory of Coal Combustion [FSKLCCA2108]
  3. Hubei Key Laboratory of Industrial Fume and Dust Pollution Control [HBIK2019-04]
  4. Nanyang collaborative innovation project (Nanyang Research Institute of Zhengzhou University) [NRIZU2020CIP0006]

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Through a comprehensive study of biomass fluidized bed devices and fast pyrolysis experiments to produce bio-oil, optimal production parameters were determined. The analysis of bio-oil properties revealed differences between first-level and second-level bio-oil. Energy consumption mainly went towards preheating and cooling nitrogen, but byproducts such as coke and non-condensable gas could be utilized for self-heating production.
Based on a comprehensive study of biomass fluidized bed device, a fast pyrolysis experiment to produce bio-oil was carried out using rice husks as raw material. The effects of reaction temperature, fluidized gas volume, and feed rate on the yield of bio-oil were studied. Experiments showed that the best temperature for bio-oil yield was 500 degrees C, the best fluidizing gas flow rate was 22 m3/h and the best feed rate was 2.65 kg/h. The physical and chemical properties of bio-oil were analyzed, and the results showed that the density, acidity, calorific value, and viscosity of the first-level bio-oil were greater than those of the second-level bio-oil. Among the components, the contents of acids (18.74%), ketones (22.51%), esters (16.90%), and phenols (17.91%) were relatively high. Aspen Plus software was used to analyze the energy consumption of the reaction model. Most of the energy in the fast pyrolysis of biomass is consumed for the preheating and cooling of nitrogen, which accounts for 60% of the total energy consumption. The combustion of the coke and non-condensable gas, which are produced as byproducts can be used for preheating raw materials to realize self-heating production. Combine experiment and simulation will promote its industrialization.

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