Strategies of dispersive liquid-liquid microextraction for coastal zone environmental pollutant determination

Coastal zone means the interface of land and sea, and therefore, environmental pollutants steaming from land-based activities (like manufactories) and sea-based activities (like shipping) are all existing in coastal zone. These pollutants usually have characteristics of low residues, complicated matrices, easy accumulation and so on, causing difficulty to detect coastal pollutants quickly and sensitively. It is imperative to perform effective sample preparation prior to instrumental analysis. Dispersive liquid-liquid microextraction (DLLME) has attracted significant research interest for sample preparation, owing to its high enrichment ability, low reagent/sample consumption, and wide analyte/matrix applicability, as well as robustness, simplicity, rapidity and inexpensiveness. Herein, we comprehensively review the recent advancements of DLLME technology and its analytical parameters including enrichment principles, extraction modes, and practical application; the emphasis is on novel mode-construction and representative coastal-environmental pollutants extraction. Construction strategies are highlighted by classifying DLLME into five major modes, according to extractant's types, including normal ones, low density solvents, ionic liquids, deep eutectic solvents and others. The coupling of DLLME with other extraction techniques like solid-phase extraction is also briefly introduced. The strengths and weaknesses of each strategy and its rationality are also elaborated. In addition, some typical applications of the different DLLME modes for the determination of organic compounds and heavy metals in coastal water, sediment, soil, and biota are summarized. The increasingly concerned green aspects and instrumentation of DLLME are presented, and finally, the challenges and perspectives of the DLLME for environmental analysis are proposed. (c) 2021 Elsevier B.V. All rights reserved.

Automated summary

Coastal zones are exposed to pollutants from both land-based and sea-based activities, making it challenging to detect coastal pollutants quickly and sensitively. Dispersive liquid-liquid microextraction (DLLME) is an important sample preparation technique for environmental analysis due to its high enrichment ability, low reagent consumption, and wide applicability.