Journal
JOURNAL OF CHEMICAL PHYSICS
Volume 155, Issue 13, Pages -Publisher
AIP Publishing
DOI: 10.1063/5.0060171
Keywords
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Funding
- Academia Sinica
- Ministry of Science and Technology of Taiwan [MOST 109-2113-M-001-021, MOST 110-2113-M-001-053]
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In this study, a simple and accurate method for estimating light-matter coupling strength and optical loss without free parameters was presented using macroscopic quantum electrodynamics (MQED) combined with a pseudomode approach. It was analytically and numerically proven that the dynamics derived from the MQED-based wavefunction approach is mathematically equivalent to the dynamics governed by the CQED-based Lindblad master equation when the Purcell factor behaves like Lorentzian functions.
Light-matter coupling strength and optical loss are two key physical quantities in cavity quantum electrodynamics (CQED), and their interplay determines whether light-matter hybrid states can be formed or not in chemical systems. In this study, by using macroscopic quantum electrodynamics (MQED) combined with a pseudomode approach, we present a simple but accurate method, which allows us to quickly estimate the light-matter coupling strength and optical loss without free parameters. Moreover, for a molecular emitter coupled with photonic modes (including cavity modes and plasmon polariton modes), we analytically and numerically prove that the dynamics derived from the MQED-based wavefunction approach is mathematically equivalent to the dynamics governed by the CQED-based Lindblad master equation when the Purcell factor behaves like Lorentzian functions.
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