4.7 Article

Correlated escape of active particles across a potential barrier

Journal

JOURNAL OF CHEMICAL PHYSICS
Volume 155, Issue 23, Pages -

Publisher

AIP Publishing
DOI: 10.1063/5.0074072

Keywords

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Funding

  1. MIUR PRIN [201798CZLJ]
  2. Alexander von Humboldt Foundation

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By studying the dynamics of one-dimensional active particles in a double-well potential, we observed that the escape properties of the system are influenced by the persistence time of the active force and the swim velocity. The non-monotonic behavior of mean escape time with respect to activity persistence time indicates an optimal parameter choice for the escape process. Additionally, the interaction of active and repulsive forces in the escape of two mutually repelling active particles can lead to correlated motion that favors simultaneous barrier crossing.
We study the dynamics of one-dimensional active particles confined in a double-well potential, focusing on the escape properties of the system, such as the mean escape time from a well. We first consider a single-particle both in near and far-from-equilibrium regimes by varying the persistence time of the active force and the swim velocity. A non-monotonic behavior of the mean escape time is observed with the persistence time of the activity, revealing the existence of an optimal choice of the parameters favoring the escape process. For small persistence times, a Kramers-like formula with an effective potential obtained within the unified colored noise approximation is shown to hold. Instead, for large persistence times, we developed a simple theoretical argument based on the first passage theory, which explains the linear dependence of the escape time with the persistence of the active force. In the second part of the work, we consider the escape on two active particles mutually repelling. Interestingly, the subtle interplay of active and repulsive forces may lead to a correlation between particles, favoring the simultaneous jump across the barrier. This mechanism cannot be observed in the escape process of two passive particles. Finally, we find that in the small persistence regime, the repulsion favors the escape, such as in passive systems, in agreement with our theoretical predictions, while for large persistence times, the repulsive and active forces produce an effective attraction, which hinders the barrier crossing.

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