4.6 Article

Sedimentary environment and organic matter enrichment of black mudstones from the upper Triassic Chang-7 member in the Ordos Basin, Northern China

Journal

JOURNAL OF ASIAN EARTH SCIENCES
Volume 224, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jseaes.2021.105009

Keywords

Black mudstone; Geochemistry characteristics; Paleo-sedimentary environment; Organic matter characteristics; Chang-7 Member; Ordos Basin

Funding

  1. National Science and Technology Major Project of the Ministry of Science and Technology [2016ZX0504605-001]

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The black mudstone of the Chang-7 Member in the Ordos Basin is the most important source rock with good hydrocarbon generation potential. The sedimentary environment was semi-arid and semihumid, with continental freshwater, and an average paleotemperature of 16 degrees C. The medium-high primary productivity and suitable sedimentary environment played important roles in the enrichment and preservation of organic matter in the Chang-7 Member.
The black mudstone of the Chang-7 Member is the most important source rock in the Ordos Basin. In order to understand the paleo-climate, weathering, redox conditions, salinity, water temperature, water depth, and primary productivity under which black mudstone of the Chang-7 Member was deposited, we have analyzed total organic carbon (TOC), rock pyrolysis parameters, major elements, and trace elements of 60 black mudstone samples from the Chang-7 Member of the Yanchang Formation in the Ordos Basin. Geochemical indicators such as TOC, volatile hydrocarbon and residual hydrocarbon (S1 + S2), hydrogen index (HI), chloroform asphalt A, maximum pyrolysis peak temperature (Tmax), Vitrinite reflectance (Ro), kerogen macerals, and other organic indicators, show that the kerogen type of the Chang-7 Member was type I-II1, the thermal evolution of organic matter was in the mature stage, and it has good hydrocarbon generation potential. The major and trace element characteristics, such as C-value, Sr/Cu, Rb/Sr and Mg/Ca ratios, chemical alteration index(CIA), Sr/Ba, B, Ga-BRb trace element triangle, B/Ga, 1000 x Rb/K2O, V/(V + Ni), pristane/phytane ratio (Pr/Ph), foraminiferal Mg/ Ca, and Co values indicate that the sedimentary environment of the Chang-7 Member was semi-arid and semihumid, with continental freshwater, a reductive sedimentary environment, and an average paleotemperature of 16 degrees C. Based on the analysis of Baxs and Ba/Al ratio, the Chang-7 Member has medium-high primary productivity, which together with the sedimentary environment, played an important role in the enrichment and preservation of organic matter.

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