Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 894, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2021.162313
Keywords
Double perovskites; Half metallic ferromagnetism; Spintronics; Double exchange mechanism; Electrical conductivity
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Funding
- Taif University, Taif, Saudi Arabia [TURSP-2020/200]
- Deanship of Scientific Research at King Khalid University [R.G.P.2/171/42]
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The study comprehensively investigated the structural, electronic, magnetic, and thermal transport properties of cubic double perovskites Rb(2)Z(Cl/Br)(6) (Z = Ta, W, Re), exploring phenomena such as half metallic ferromagnetism, spin polarization, and thermal transport.
The charge and spin degrees of freedom of electrons employed together introduce a new field of electronics, known as spintronics, which has multifunctional applications in data storage, control, and transfer in supercomputing. In this perspective, we have comprehensively investigated cubic double perovskites Rb(2)Z(Cl/Br)(6) (Z = Ta, W, Re). More precisely, we explored their structural, electronic, magnetic, and thermal transports. The structural stability is addressed by a tolerance factor, enthalpy of formation, and Curie temperature calculations. Half metallic ferromagnetism (HMF), quantum exchange process, spin polarization, and exchange energies are explained in terms of hybridization and double exchange mechanism. Furthermore, spin-polarized thermal transports are revealed by investigating thermal conductivity, Seebeck coefficient, and power factor. (C) 2021 Elsevier B.V. All rights reserved.
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