4.7 Article

Towards high performance in Ti-based composite through manipulating nickel coatings on graphene reinforcement

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 893, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2021.162240

Keywords

Metal matrix composites; Graphene nanoflakes; Electroless nickel plating; Interface design; Mechanical properties

Funding

  1. China Postdoctoral Science Foundation [2020M670154]

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The study investigates the effect of nickel coating microstructure of graphene nanoflakes on strengthening titanium matrix composites. Nickel-coated graphene nanoflakes were produced and incorporated into Ti bulk composites, leading to improved strength and ductility. Partially nickel-coated GNFs exhibited the highest tensile strength and may offer new strategies for high-performance TMCs through interfacial microstructure design.
Graphene nanoflakes (GNFs) surface metallization is a potential method to simultaneously achieve homogeneous GNFs dispersion and suitable interfacial bonding in metal matrix composites (MMCs). In this study, the effect of nickel coating microstructure of GNFs on strengthening titanium matrix composites (TMCs) was investigated. To this end, nickel-coated graphene nanoflakes (Ni-GNFs) with two different states were produced via electroless plating. The Ni-GNFs/Ti bulk composites were consolidated by com-bining short-time ball milling, spark plasma sintering (SPS) and hot rolling (HR). Results showed that the reinforcements were well dispersed in the Ni-GNFs/Ti composites coupled with remarkably strength im-provement, which resulted from the precipitation of NiTi2 intermetallic compound and strong interfacial bonding. The partially Ni-coated GNFs have a better strengthening effect than fully Ni-coated GNFs in TMCs, which was closely associated with the formation of a special interfacial microstructure. As a result, the composite with partially Ni-coated GNFs exhibited the highest tensile strength of 821 MPa, as well as excellent ductility (similar to 18.3%). This finding may provide new strategies for the preparation of high-perfor-mance TMCs through interfacial microstructure design. (C) 2021 Elsevier B.V. All rights reserved.

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