4.7 Article

Energy storage properties of composite films with relaxor antiferroelectric behaviors

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 881, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2021.160576

Keywords

Ferroelectrics films; Energy storage; Relaxor antiferroelectric; PbZrO3; Ba2Bi4Ti5O18

Funding

  1. National Natural Science Foundation of China [12074204, 11864028]

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BBT/PZ/BBT composite films based on relaxor ferroelectric and antiferroelectric materials demonstrate high energy storage performance with a large recoverable energy storage density and efficiency, as well as stable behavior under various temperature and frequency ranges.
Here, typical relaxor ferroelectric Ba2Bi4Ti5O18 (BBT) and antiferroelectric PbZrO3 (PZ) were selected to form BBT/PZ/BBT composite films for high energy storage performance. The composite films exhibit relaxor antiferroelectric behavior at 1000 kV/cm. A large recoverable energy storage density (W-rec) of 66.7 J/cm(3) and efficiency (eta) of 65.6% were achieved at 2500 kV/cm in BBT/PZ/BBT composite films. Additionally, the variation of W-rec and eta was less than 4% after 5 x 10(7) charge-discharge cycles at 1000 kV/cm. What's more, the energy storage performance of composite films is stable under the temperature range from 20 degrees C to 160 degrees C and frequency range from 500 Hz to 2000 Hz. (C) 2021 Elsevier B.V. All rights reserved.

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