4.7 Article

One pot synthesis and electromagnetic interference shielding behavior of reduced graphene oxide nanocomposites decorated with Ni0.5Co0.5Fe2O4 nanoparticles

Journal

JOURNAL OF ALLOYS AND COMPOUNDS
Volume 887, Issue -, Pages -

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2021.161472

Keywords

Microwave absorption; Nanocomposites; Reduced graphene oxide; EMI shielding; Ferrites

Funding

  1. UGC, University Grants Commission, India New Delhi
  2. DST, Department of Science and Technology, India New Delhi [F530/5/DRS/2012 (SAP-1), SR/FST/PSI-162/2011]
  3. MDU Rohtak under R.K. Fund [DSW/2018/537]

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This study presents a facile method for synthesizing Ni0.5Co0.5Fe2O4 nanoparticles decorated reduced graphene oxide (RGO) nanocomposites, which exhibit enhanced shielding effectiveness and absorption performance. The findings suggest that the interface linkages and synergy between Ni0.5Co0.5Fe2O4 and RGO play a crucial role in improving the microwave absorbing properties, thereby advancing the design of lightweight microwave absorbers.
With the rapid evolution of wireless communication technology, microwave absorbing materials having broad frequency bandwidth has been at center stage. Present article reports the direct facile method for synthesis of Ni0.5Co0.5Fe2O4 nanoparticles decorated reduced graphene oxide (RGO) nanocomposites (NG) by insitu genesis of Ni0.5Co0.5Fe2O4 nanoparticles in graphene oxide heterogeneous mixture, preceded by hydrazine reduction and calcination. Because of magnetic Ni0.5Co0.5Fe2O4 and dielectric reduced graphene oxide, the intercalated microstructure of NG nanocomposites shows increased shielding effectiveness due to absorption with major contribution from strong conduction loss, polarization effects, enhanced attenuation ability, eddy current losses and multiple scattering. Consequently, the shielding effectiveness of 36.3 dB (similar to 99.98% attenuation of the electromagnetic wave) has been attained in 12.4-18 GHz for a corresponding thickness of 2 mm. The results indicates that the interface linkages and synergy among Ni0.5Co0.5Fe2O4 and RGO plays an important role in improvement of microwave absorbing properties and hence in designing of lightweight microwave absorbers. (C) 2021 Elsevier B.V. All rights reserved.

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