Effect of Jahn-Teller distortion on microstructural and dielectric properties of La based double perovskites

The double perovskite La(2)FeMn(1-x)CuxO(6) ((x = 0.1, 0.2, 0.3, 0.4 and 0.5) was synthesized by using conventional solid-state reaction method. The crystal structure of the double perovskite was confirmed to be orthorhombic (Pnma) by Rietveld refinement of the powder X-ray diffraction. The average grain sizes of the prepared samples were calculated to be in the range of 0.5-1 mu m. Energy dispersive x-ray spectroscopy confirmed the presence of La, Fe, Mn, Cu and O in the samples. Jahn-Teller distortion plays a crucial role in the structural distortion of the system. Due to the ionic radii mismatch of the B-site substituents, an extra Raman mode was identified for substituted systems. The frequency dependence of dielectric, AC conductivity and impedance spectroscopy were investigated at different temperatures within the frequency range 10 Hz to 1 MHz. We observe a Maxwell -Wagner type of polarization in the variation of the dielectric constant. A non-Debye relaxation behaviour was observed in the Nyquist plot. From the behaviour of frequency exponent with temperature, the conduction mechanism was described by the Correlated Barrier Hopping model (CBH). (C) 2021 Elsevier B.V. All rights reserved.

Automated summary

The study investigated the synthesis, crystal structure, grain size, and dielectric, conductivity, and impedance properties of the double perovskite La(2)FeMn(1-x)CuxO(6). Analysis confirmed the orthorhombic crystal structure and presence of La, Fe, Mn, Cu, and O in the samples. The article discusses the conduction mechanism and polarization behavior of the material under different temperatures.