Journal
JOURNAL OF ALLOYS AND COMPOUNDS
Volume 888, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2021.161626
Keywords
Iron-based nanostructures; Li-ion batteries; High specific capacity; Anode; Lithiation-induced activation
Categories
Funding
- Norte Portugal Regional Operational Programme (NORTE2020), under the Portugal 2020 Partnership Agreement through the European Regional Development Fund (ERDF) [NORTE-01-0145-FEDER-000019]
- FCT - UT Austin Programme [UTAP-EXPL/CTE/0008/2017]
- Fundacao para a Ciencia e a Tecnologia (FCT) through FCT Investigator Grant [IF/01595/2014]
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The lithium storage performance of low-cost iron-based nanostructures, including FeOOH nanorods, Fe2O3, and FeP nanotubes, was comprehensively investigated at high charge/discharge rates. The study found that these materials exhibited increasing specific capacity and good stability over multiple charge/discharge cycles, showing potential for high-performance anodes in long-lived lithium-ion batteries.
Lithium storage performance of low-cost iron-based nanostructures including FeOOH nanorods (NRs) as well as Fe2O3 and FeP nanotubes (NTs) at high charge/discharge rates is comprehensively investigated. Although they show a low specific capacity at a rate of 1000 mA g(-1) in the beginning of cycling test, it is found that the specific capacity increases as the cycling proceeds, and can eventually reach an exceptionally high value of 1670, 1644 and 1897 mAh g(-1) for FeOOH NRs, Fe2O3 NTs and FeP NTs, respectively, after 1200 charge/discharge cycles. Moreover, even at a higher charge/discharge current density of 3000 mA g(-1), FeOOH NRs, Fe2O3 NTs and FeP NTs can still deliver an impressive specific capacity of 419.4, 459.7 and 603.4 mAh g(-1), respectively, upon 1400 charge/discharge cycles. The lithiation-induced activation process reported here offers a new perspective in designing high-performance anodes for long-lived lithium-ion batteries. (C) 2021 Elsevier B.V. All rights reserved.
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