Journal
INTERNATIONAL MATERIALS REVIEWS
Volume 67, Issue 7, Pages 734-764Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/09506608.2021.2006968
Keywords
Al-air batteries; energy storage; al anode; Al alloys; Air cathode; electrolyte; Electrolyte additives; oxygen reduction reaction
Categories
Funding
- Fundamental Research Funds for the Central Universities [FRF-TP-17-002C2]
- National Natural Science Foundation of China [51704020, 51874019, 51674025, 51725401, 51874035]
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Metal-air batteries, especially those utilizing aluminum as the metal component, are viewed as promising battery prototypes due to their high specific capacity, energy density and the availability of air. Despite the advantages of aluminum, such as its abundant reserve, low price, high theoretical capacity and energy density, there are still scientific and technical challenges that need to be overcome for commercialization. This review highlights recent progress in Al-air batteries and addresses the challenges, providing guidance for future advancements in the field.
Metal-air batteries have been considered as promising battery prototypes due to their high specific capacity, energy density and easily available nature of air. Al can be regarded as an attractive candidate because of its abundant reserve (the most abundant metal element in the earth's crust), low price (1.9 USD.kg(-1)), high theoretical capacity density of 2.98 Ah.g(-1) and high energy density of 8.1 Wh.g(-1). For meeting the level of commercialization, nevertheless, there are still many scientific and technical challenges to overcome in the Alair batteries. In this review, a comprehensive overview of Al-air batteries is initially provided, along with highlighting recent progresses in high-performance Al anodes, advanced air cathodes and improved electrolytes for Al-air batteries. The analysis and discussion on the progresses and challenges for Al-air batteries here are expected to provide a meaningful guide for future efforts to boost Al-air batteries.
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