Journal
INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS
Volume 29, Issue 2, Pages 218-227Publisher
SPRINGER
DOI: 10.1007/s12613-020-2161-6
Keywords
ammonia leaching; leaching kinetics; selective extraction; cobalt
Categories
Funding
- National Nature Science Foundation of China [51804136, 52064021, 51974140, 52064018]
- Key Projects of Jiangxi Key RD Plan, China [20192ACB70017]
- Jiangxi Provincial Cultivation Program for Academic and Technical Leaders of Major Subjects, China [20204 BCJL23031]
- Jiangxi Province Science Fund for Distinguished Young Scholars, China [20202ACB213002]
- Program of Qingjiang Excellent Young Talents, Jiangxi University of Science and Technology, China [JXUSTQJBJ 2020004]
- Distinguished Professor Program of Jinggang Scholars in institutions of higher learning, Jiangxi Povince, China
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An ammonia-based system was utilized to selectively leach cobalt (Co) from an African high-silicon low-grade Co ore, while inhibiting other elemental impurities from leaching. The process was shown to be simple and environmentally friendly, achieving a Co leaching ratio of up to 95.61% using (NH4)(2)SO4 under specific conditions. The leaching kinetics of Co indicated that the process was controlled by an interfacial chemical reaction, and a developed model was established to express the leaching behavior of Co.
An ammonia-based system was used to selectively leach cobalt (Co) from an African high-silicon low-grade Co ore, and the other elemental impurities were inhibited from leaching in this process. This process was simple and environmentally friendly. The results revealed that the leaching ratio of Co can reach up to 95.61% using (NH4)(2)SO4 as a leaching agent under the following materials and conditions: (NH4)(2)SO4 concentration 300 g/L, reductant dosage 0.7 g, leaching temperature 353 K, reaction time 4 h, and liquid-solid ratio 6 mL/g. The leaching kinetics of Co showed that the apparent activation energy of Co leaching was 76.07 kJ/mol (i.e., in the range of 40-300 kJ/mol). This indicated that the leaching of Co from the Co ore was controlled by an interfacial chemical reaction, and then the developed leaching kinetics model of the Co can be expressed as 1- (1- alpha)(1/3) = 28.01 x 10(3)x r(0)(-1) x C-(NH4)2SO4(1.5) x exp(-76073/8.314T) x t, where alpha is the leaching ratio (%) of Co, r(0) is the average radius (m) of the Co ore particles, T is the temperature (K), and C-(NH4)2SO4 is the initial reactant concentration (kg/m(3)).
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