4.7 Article

Tailoring the H2 gas detection range of the AlGaN/GaN high electron mobility transistor by tuning the Pt gate thickness

Journal

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 47, Issue 3, Pages 2050-2058

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2021.10.229

Keywords

LOD; Saturation concentration; Selectivity; FET; Fine-tuning

Funding

  1. National Natural Science Foundation of China [62071307, 61504084]
  2. Shenzhen Science & Technology Project [JCYJ2018050 7182106754]

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In this study, the fine-tuning of the H-2 gas detection range of the AlGaN/GaN HEMT devices was achieved by adjusting the Pt gate thickness. Results showed that the change in gate thickness had a significant impact on the response and response time of the devices.
H-2 gas sensors for different applications require various detection ranges, such as 1-100 ppm for exhale breath test and 0-40000 ppm for H-2 energy vehicles. Coarse-tuning of the detection range could be realized by the selection of the type of H-2 sensors. The finetuning of the detection range within one type of H-2 sensor, however, is little concerned and reported. Herein, we propose to achieve the fine-tuning of the H-2 gas detection range of the AlGaN/GaN HEMT devices by adjusting the Pt gate thickness. Devices with various Pt gate thicknesses of 2, 20, 60, and 100 nm were fabricated and investigated. Results show that the HEMT devices have excellent pinch-off characteristic with an on-to-off ratio of similar to four orders of magnitude. For the 100 nm thick device exposed to 500 ppm H-2, ultrafast response time of 1.5 s is observed together with high response. With the decrease of gate thickness, both the response and the response time gradually increase, 1850% and 6 s for the 2 nm thick device. Moreover, both the low limit of detection (LOD) and the saturation cencentration decrease from 1.6 to 0.14 ppm and from 30,000 to 5000 ppm, respectively, with the gate thickness reduced from 100 to 2 nm, revealing that fine-tuning of the detection range could be achieved by adjusting the gate thickness. Finally, the response activation energy is also studied, 15.9, 19.7, and 42.8 kJ/mol for 2, 60, and 100 nm thick devices, respectively. (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

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