Journal
BULLETIN OF MATERIALS SCIENCE
Volume 38, Issue 1, Pages 151-156Publisher
INDIAN ACAD SCIENCES
DOI: 10.1007/s12034-014-0821-8
Keywords
Gel polymer electrolyte; electrochemical analysis; structural properties; thermogravimetry
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Funding
- Union Grants Commission (UGC), Government of India [40-459/2011(SR)]
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Polymer blend composed of poly(vinyl chloride) and poly(ethyl methacrylate) with lithium perchlorate (LiClO4) and the plasticizer ethylene carbonate (EC) mixture with propylene carbonate, gamma-butyrolactone (GBL), dibutyl phthalate and diethyl carbonate have been synthesized using the solution casting technique. Structural changes and thermal stability of the films were resolved using X-ray diffraction analysis and thermogravimetric/differential thermal analysis, respectively. The membrane that contains EC+ GBL exhibits maximum ionic conductivity of the order of 1.208x10(-3) S cm(-1) at 303 K. The temperature-dependent ionic conductivity of the polymer membranes has been estimated using AC impedance analysis.
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