Journal
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
Volume 47, Issue 8, Pages 5326-5336Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2021.11.180
Keywords
Chevrel phases; Cu2Mo6S8; Oxygen reduction reaction; Density functional theory; Lattice dynamic properties
Categories
Funding
- [118M662]
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This study presents the synthesis, structural characterization, and electrocatalytic properties of three different Cu2Mo6S8 structures as alternative ORR electrocatalysts. The findings show that only bare Cu2Mo6S8 exhibits excellent ORR performance comparable to state-of-the-art catalysts. Density functional theory calculations provide detailed information on the structural and electronic properties of Cu2Mo6S8.
Catalytic processes are contemplated as break point in generating alternative and sustainable energy platforms. The cathodic oxygen reduction reaction (ORR) is an important catalytic system, mainly finding practice in fuel cell and metal-air battery technologies. This work presents the synthesis, structural characterization and electrocatalytic properties of three different Cu2Mo6S8 structures as alternative ORR electrocatalysts. The effect of different carbon additives during synthesis was studied and no positive influence of the carbon addition was indicated. Our findings show that only the bare Cu2Mo6S8 enhances the ORR electro-performance to class with the state-of-the-art ORR catalysts. Excellent stability of 10,000 consecutive ORR cycles, a superior onset potential of 0.894 V and halfwave (E-1/2) potential of 0.641 V vs. reversible hydrogen electrode (RHE) increase the noteworthiness of the Cu2Mo6S8 electrodes. Aside from experimental investigations, density functional theory calculations deliver profound knowledge on the structural and electronic properties (electronic band structure, partial density of states and electron density) of Cu2Mo6S8. (C) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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