Synthesis of MOF/MoS2 composite photocatalysts with enhanced photocatalytic performance for hydrogen evolution from water splitting

With the shortage of global fossil energy and the increasing crisis of environmental deterioration, hydrogen energy has become an environmentally benign alternative as a clean energy source. In most studies on photocatalytic hydrogen production, novel photocatalytic material has played an important role to enhance the hydrogen production rate. In this study, the optimal conditions for the synthesis of MoS2 were established through series of characterizations with 190 degrees C calcination temperature and 1 wt% PEG surfactant addition. The best conditions for synthesizing MOF include copper nitrate as the copper precursor, 30% ultrasonic amplitude, and 240 degrees C calcination temperature. After adding 1 wt% MOF in MOS2, a flower-like structure with small particle size, uniform distribution, regularity, and large surface pores, has been formed, where its unit is modified with many rough, porous, and high specific surface area octahedral structures. In addition, 1MOF/MOS2 has the most negative conduction band edge (similar to 0.135 V), the smallest charge transfer resistance (R-ct = 1.78 Omega), the largest photo current (11.1 mA/cm(2)), the lowest PL spectral peak intensity, and excellent photocatalytic stability. The above morphological features and optical properties can significantly form more active sites, enhance the electron transfer rate, and inhibit the electron-hole recombination, thus making the MOF/MOS2 composite photocatalyst achieve the maximum hydrogen production capacity (626.3 mmol g(-1) h(-1)). (c) 2021 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.

Automated summary

With the shortage of global fossil energy and the increasing crisis of environmental deterioration, hydrogen energy has become an environmentally benign alternative as a clean energy source. In this study, the MOF/MOS2 composite photocatalyst demonstrated excellent photocatalytic stability and the highest hydrogen production capacity under the optimal synthesis conditions.