Preparation of chitosan crosslinked with metal-organic framework (MOF-199)@aminated graphene oxide aerogel for the adsorption of formaldehyde gas and methyl orange

Chitosan crosslinked with metal-organic framework (MOF-199)@aminated graphene oxide aerogel (MOF199@AFGO/CS) were prepared to adsorb formaldehyde and methyl orange. The prepared MOF-199@AFGO/CS aerogel was well characterized via SEM, EDX, FT-IR, XRD and XPS to reveal the microstructure and composition. Besides, the mechanical property and the stability of MOF-199@AFGO/CS aerogel were investigated. The results showed that MOF-199@AFGO/CS aerogel had good stability in water, compression resilience and thermostability. The study on the ability to adsorb formaldehyde gas and methyl orange showed that the adsorption capacity of MOF-199@AFGO/CS aerogel was related to the pore size and the surface functional groups of MOF199@AFGO/CS aerogel. When the pore size is moderate, as the amino group and MOF-199 on the aerogel increased, the adsorption capacity of formaldehyde gas (197.89 mg/g) and methyl orange (412 mg/g) can reach the maximum. Furthermore, the adsorption process at equilibrium followed the Freundlich isotherm model. The kinetic behavior was well fitted by the pseudo-second-order model, indicating chemisorption as the ratedetermining step. This work can provide a reliable basis for the adsorbent to remove pollutants in different forms at the same time, and has potential application in simultaneously adsorbing liquid pollutants and gas pollutants.

Automated summary

The Chitosan crosslinked with MOF-199@aminated graphene oxide aerogel was prepared as an adsorbent for formaldehyde and methyl orange. Characterization and stability tests showed that the aerogel had good adsorption capacity and stability. Adsorption of pollutants followed Freundlich isotherm model and pseudo-second-order model for kinetic behavior.