Fly ash modified magnetic chitosan-polyvinyl alcohol blend for reactive orange 16 dye removal: Adsorption parametric optimization

A magnetic biocomposite blend of chitosan-polyvinyl alcohol/fly ash (m-Cs-PVA/FA) was developed by adding fly ash (FA) microparticles into the polymeric matrix of magnetic chitosan-polyvinyl alcohol (m-Cs-PVA). The effectiveness of m-Cs-PVA/FA as an adsorbent to remove textile dye (reactive orange 16, RO16) from aquatic environment was evaluated. The optimum adsorption key parameters and their significant interactions were determined by Box-Behnken Design (BBD). The analysis of variance (ANOVA) indicates the significant interactions can be observed between m-Cs-PVA/FA dose with solution pH, and m-Cs-PVA/FA dose with working temperature. Considering these significant interactions, the highest removal of RO16 (%) was found 90.3% at mCs-PVA/FA dose (0.06 g), solution pH (4), working temperature (30 degrees C), and contact time (17.5 min). The results of adsorption kinetics revealed that the RO16 adsorption was better described by the pseudo-second-order model. The results of adsorption isotherm indicated a multilayer adsorption process as well described by Freundlich model with maximum adsorption capacity of 123.8 mg/g at 30 degrees C. An external magnetic field can be easily applied to recover the adsorbent (m-Cs-PVA/FA). The results supported that the synthesized m-Cs-PVA/FA presents itself as an effective and promising adsorbent for textile dye with preferable adsorption capacity and separation ability during and after the adsorption process.

Automated summary

A magnetic biocomposite blend (m-Cs-PVA/FA) was developed by incorporating fly ash microparticles into the polymeric matrix, showing high efficiency in removing textile dye from aquatic environment. The Box-Behnken Design was used to determine the optimal adsorption parameters and significant interactions. The synthesized m-Cs-PVA/FA exhibited promising adsorption capacity and separation ability for textile dye, making it an effective adsorbent for environmental remediation.