Organosolv and ionosolv processes for autohydrolyzed poplar fractionation: Lignin recovery and characterization

Biomass fractionation plays a major role in the search for competitive biorefineries, where the isolation and recovery of the three woody fractions is key. In this sense, we have used autohydrolyzed hemicellulose-free poplar as feedstock to compare two fractionation processes, organosolv and ionosolv, oriented to lignin recov-ery. The recovered lignins were then characterize by different techniques (NMR, GPC, TGA). Both treatments were tested at different temperatures to analyze temperature influence on lignin recovery and properties. The highest lignin recovery was obtained with the ionosolv process at 135 ?, reaching a solid yield of 70%. Lignin characterization showed differences between both treatments. Lignins enriched in C-O linkages and G units were recovered with the organosolv process, where increasing temperature led to highly depolymerized lignins. However, lignins with higher C-C linkages and S units contents were obtained with the ionosolv process, pro-ducing more thermically stable lignins. In addition, increasing temperature caused lignin repolymerization when employing ionic liquids as solvents. Therefore, this work outlines the most important differences between ionosolv and organosolv processes for biomass fractionation, focusing on lignin recovery and its properties, which is the first step in order to valorize all biomass fractions.

Automated summary

Biomass fractionation plays a crucial role in the development of competitive biorefineries, especially in the isolation and recovery of lignin. This study compared two fractionation processes, organosolv and ionosolv, using autohydrolyzed hemicellulose-free poplar as feedstock. The results showed that the ionosolv process at higher temperature achieved higher lignin recovery and produced more thermally stable lignin. The two processes had different effects on lignin recovery and properties.