4.6 Article

CaCO3 derived from eggshell waste for improving the hardness values and wear behavior of composite coating on mild steel via co-deposition

Journal

Publisher

SPRINGER LONDON LTD
DOI: 10.1007/s00170-021-08492-3

Keywords

Eggshell; Wear; Response surface; Mild steel and microstructure

Funding

  1. Africa Centre of Excellence for Sustainable Power and Energy Development, ACE-SPED, University of Nigeria, Nsukka
  2. Faculty of Engineering and Built Environment, University of Johannesburg, Auckland Park, South Africa

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This study aimed to utilize eggshells as a source of CaCO3 to improve the hardness and wear behavior of composite coating on mild steel. The results showed that the Zn-CaCO3-derived eggshell particles composite coatings successfully improved hardness values and exhibited lower friction coefficients. The study suggests that the Zn-20 g CaCO3-derived eggshell particles composite coating can be used in applications where wear and roller body are important considerations.
The increased demands for eggs for consumption have large increases in the deposition of eggshells as environmental pollution worldwide and increase high management costs. To reduce the management costs of eggshells, this work attempt was made to utilize eggshells as a source of CaCO3 for improving the hardness values and wear behavior of composite coating on mild steel. The composite coating was produced using 0, 5, 10, 15, and 20 g CaCO3-derived eggshell particles. The response surface method was used to determine the influences of applied load, sliding speed, and weight of CaCO3-derived eggshell particles on the wear behavior. The results have shown that Zn- CaCO3-derived eggshell particles composite coatings were successfully formed on mild steel. A 90.17% improvement of hardness values was obtained at Zn-20 g CaCO3-derived eggshell particles. The Zn-20 g CaCO3-derived eggshell particles sample has a lower friction coefficient. Wear rate increase with the increase in applied load and sliding speed. The optimum condition was obtained at CaCO3-derived eggshell particles (+ 1), applied load (- 0.35), and speed (- 0.58) with the lowest wear rate of 0.99 mm(3)/Nm. It has been recommended that the Zn-20 g CaCO3-derived eggshell particles composite coating of mild steel can be used in areas where wear and roller body are paramount.

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