Journal
INORGANIC CHEMISTRY COMMUNICATIONS
Volume 132, Issue -, Pages -Publisher
ELSEVIER
DOI: 10.1016/j.inoche.2021.108807
Keywords
Single-ion Magnet; Octahedral Coordination Geometry; ZFC-FC measurements; ab initio calculations
Categories
Funding
- NSFC [21620102002, 21822508]
- Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program [2017BT01C161]
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In this study, a {Zn2Dy} single-ion magnet with octahedral coordination geometry (O-h) was synthesized and characterized. Magnetic susceptibility measurements revealed magnetic blocking below 4.1 K. Combining experimental data and ab initio calculations, the dynamic relaxation characteristics of this complex were detailed.
A {Zn2Dy} single-ion magnet (SIM) with octahedral coordination geometry (O-h) was synthesized and characterized. The zero-field-cooled (ZFC) and field-cooled (FC) magnetic susceptibility measurement diverged below 4.1 K, revealing the presence of the magnetic blocking. Combining experimental data and ab initio calculations, we depicted the dynamic relaxation characters of this complex in detail.
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