Journal
INORGANIC CHEMISTRY
Volume 60, Issue 20, Pages 15085-15090Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.1c01349
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Funding
- National Natural Science Foundation of China (NSFC) [21471113, 21501133]
- Tianjin 131 Innovative Talent
- NSFC [22071049]
- China Hunan Provincial Science & Technology Department [2020RC3020]
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A novel three-dimensional copper-organic framework with high sensitivity and selectivity towards dysprosium ion (Dy3+) and luminescent quenching towards cyano compounds has been designed and synthesized, showing potential as a luminescent probe for various inorganic and organic compounds.
Luminescent probes have been used for the detection of various heavy metals and toxic compounds. A novel sensor with excellent sensitivity and selectivity is in high demand. Herein, we designed and synthesized a three-dimensional copper-organic framework of pcu alpha-Po primitive cubic topology with a Schlafli symbol of {4.4.4.4.4.4.4.4.4.4.4.4.*.*.*}. By taking advantage of metal clusters and a triazole ligand as the metal-organic framework (MOF) components, the newly obtained MOF is stable in various environments and can be potentially used as the sensor. Remarkably, this MOF-based sensor shows high sensitivity and selectivity toward a dysprosium ion (Dy3+) in a multiple-lanthanide mixed solution. Besides, it exhibits luminescent quenching toward various cyano compounds. This chiral cluster-based network provides a potential luminescent probe for various inorganic and organic compounds with high sensitivity and selectivity.
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