4.7 Article

Reductive Reactivity of the 4f75d1 Gd(II) Ion in {GdII[N(SiMe3)2]3}-: Structural Characterization of Products of Coupling, Bond Cleavage, Insertion, and Radical Reactions

Related references

Note: Only part of the references are listed.
Article Chemistry, Multidisciplinary

Delivery of a Masked Uranium(II) by an Oxide-Bridged Diuranium(III) Complex

Dieuwertje K. Modder et al.

Summary: Researchers synthesized and characterized U-III/U-IV and U-III/U-III complexes, finding that the U-O bond can be easily broken upon addition of N-heterocycles, releasing U-III and U-II. Particularly, the U-III/U-III oxide complex exhibits unique reductive coupling and two-electron reduction reactivity.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

Article Chemistry, Multidisciplinary

A Molecular Low-Coordinate [Fe-S-Fe] Unit in Three Oxidation States

Christian Schneider et al.

Summary: This study reports a dinuclear monosulfido bridged diiron(II) complex with a similar [Fe-S-Fe] core geometry that can be stepwise oxidized to different oxidation states while retaining the core structure. The cleavage of the [Fe-S-Fe] unit by CS2 is also demonstrated in this research. The complexes have been characterized crystallographically and electron structures have been studied using various techniques such as Fe-57 Mossbauer spectroscopy and SQUID magnetometry.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Article Chemistry, Inorganic & Nuclear

A Room-Temperature Stable Y(II) Aryloxide: Using Steric Saturation to Kinetically Stabilize Y(II) Complexes

Samuel A. Moehring et al.

INORGANIC CHEMISTRY (2020)

Article Chemistry, Multidisciplinary

Formation of the End-on Bound Lanthanide Dinitrogen Complexes [(R2N)3Ln-N=N-Ln(NR2)3]2- from Divalent [(R2N)3Ln]1- Salts (R = SiMe3)

Austin J. Ryan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2020)

Article Chemistry, Inorganic & Nuclear

Trapping CS22- and S32- between Two Ytterbium Formamidinates

Daniel Werner et al.

INORGANIC CHEMISTRY (2019)

Article Chemistry, Multidisciplinary

CS2 Reductive Coupling to Acetylenedithiolate by a Dinuclear Ytterbium(II) Complex

Davide Toniolo et al.

CHEMISTRY-A EUROPEAN JOURNAL (2019)

Article Chemistry, Inorganic & Nuclear

Group 4 Metal and Lanthanide Complexes in the Oxidation State+3 with Tris(trimethylsilyl)silyl Ligands

Rainer Zitz et al.

INORGANIC CHEMISTRY (2019)

Article Chemistry, Multidisciplinary

Isolation of a Square-Planar Th(III) Complex: Synthesis and Structure of [Th(OC6H2tBu2-2,6-Me-4)4]1-

Daniel N. Huh et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Inorganic & Nuclear

Synthesis and structural characterization of lanthanum and cerium substituted cyclopentadienyl borohydride complexes

Fabrizio Ortu et al.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2018)

Article Chemistry, Multidisciplinary

Actinide-Pnictide (An-Pn) Bonds Spanning Non-Metal, Metalloid, and Metal Combinations (An=U, Th; Pn=P, As, Sb, Bi)

Thomas M. Rookes et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

Article Chemistry, Multidisciplinary

End-On Bridging Dinitrogen Complex of Scandium

David H. Woen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Synthesis and Electronic Structures of Heavy Lanthanide Metallocenium Cations

Conrad A. P. Goodwin et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Inorganic & Nuclear

Reactivity of Complexes of 4fn5d1 and 4Fn+1 Ln2+ Ions with Cyclooctatetraene

Chad T. Palumbo et al.

ORGANOMETALLICS (2017)

Article Chemistry, Multidisciplinary

Comparisons of lanthanide/actinide+2 ions in a tris(aryloxide)arene coordination environment

Megan E. Fieser et al.

CHEMICAL SCIENCE (2017)

Article Chemistry, Multidisciplinary

Solution Synthesis, Structure, and CO2 Reduction Reactivity of a Scandium(II) Complex, {Sc[N(SiMe3)2]3}-

David H. Woen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Article Chemistry, Multidisciplinary

Double Reduction of 4,4′-Bipyridine and Reductive Coupling of Pyridine by Two Thorium(III) Single-Electron Transfers

Alasdair Formanuik et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

Article Chemistry, Inorganic & Nuclear

Physicochemical Properties of Near-Linear Lanthanide(II) Bis(silylamide) Complexes (Ln = Sm, Eu, Tm, Yb)

Conrad A. P. Goodwin et al.

INORGANIC CHEMISTRY (2016)

Editorial Material Chemistry, Inorganic & Nuclear

An Editorial About Elemental Analysis

Francois P. Gabbai et al.

ORGANOMETALLICS (2016)

Article Chemistry, Multidisciplinary

The first near-linear bis(amide) f-block complex: a blueprint for a high temperature single molecule magnet

Nicholas F. Chilton et al.

CHEMICAL COMMUNICATIONS (2015)

Article Chemistry, Inorganic & Nuclear

CS2 activation at uranium(III) siloxide ate complexes: the effect of a Lewis acidic site

Clement Camp et al.

DALTON TRANSACTIONS (2015)

Article Chemistry, Inorganic & Nuclear

Reactivity of the Ln2+ Complexes [K(2.2.2-cryptand)][(C5H4SiMe3)3Ln]: Reduction of Naphthalene and Biphenyl

Christopher M. Kotyk et al.

ORGANOMETALLICS (2015)

Article Chemistry, Multidisciplinary

Tuning Lanthanide Reactivity Towards Small Molecules with Electron-Rich Siloxide Ligands

Julie Andrez et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

Article Chemistry, Inorganic & Nuclear

Reactivity of Organothorium Complexes with TEMPO

Ryan R. Langeslay et al.

INORGANIC CHEMISTRY (2014)

Article Chemistry, Inorganic & Nuclear

Reactivity of Bulky Formamidinatosamarium(II or III) Complexes with C=O and C=S Bonds

Glen B. Deacon et al.

INORGANIC CHEMISTRY (2014)

Article Chemistry, Inorganic & Nuclear

Tetrakis(bis(trimethylsilyl)amido)uranium(IV): Synthesis and Reactivity

Andrew J. Lewis et al.

INORGANIC CHEMISTRY (2013)

Article Chemistry, Multidisciplinary

Completing the Series of +2 Ions for the Lanthanide Elements: Synthesis Of Molecular Complexes of Pr2+, Gd2+, Tb2+, and Lu2+

Matthew R. MacDonald et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

Article Chemistry, Multidisciplinary

Reversible C-C Bond Formation between Redox-Active Pyridine Ligands in Iron Complexes

Thomas R. Dugan et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Article Chemistry, Multidisciplinary

Isolation of (CO)1- and (CO2)1- Radical Complexes of Rare Earths via Ln(NR2)3/K Reduction and [K2(18-crown-6)2]2+ Oligomerization

Ming Fang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Article Chemistry, Multidisciplinary

Expanding Rare-Earth Oxidation State Chemistry to Molecular Complexes of Holmium(II) and Erbium(II)

Matthew R. MacDonald et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

Article Chemistry, Multidisciplinary

Probing the Reactivity and Electronic Structure of a Uranium(V) Terminal Oxo Complex

Skye Fortier et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

Article Chemistry, Multidisciplinary

Synthesis of a Crystalline Molecular Complex of Y2+, [(18-crown-6)K][(C5H4SiMe3)3Y]

Matthew R. MacDonald et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

Article Chemistry, Inorganic & Nuclear

Low coordinate lanthanide(II) complexes supported by bulky guanidinato and amidinato ligands

Dennis Heitmann et al.

DALTON TRANSACTIONS (2010)

Article Chemistry, Multidisciplinary

Synthesis of a Nitrido-Substituted Analogue of the Uranyl Ion, [N=U=O]+

Skye Fortier et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

Article Chemistry, Multidisciplinary

Dinitrogen Reduction and C-H Activation by the Divalent Organoneodymium Complex [(C(5)H(2)tBu(3))(2)Nd(mu-I)K([18]crown-6)]

Florian Jaroschik et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)

Article Chemistry, Multidisciplinary

Lanthanum does form stable molecular compounds in the+2 oxidation state

Peter B. Hitchcock et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2008)

Article Chemistry, Inorganic & Nuclear

A Mild Protocol To Generate Uranium(IV) Mixed-Ligand Metallocene Complexes using Copper(I) Iodide

Christopher R. Graves et al.

ORGANOMETALLICS (2008)

Article Chemistry, Inorganic & Nuclear

Utility of anhydrous neodymiurn nitrate as a precursor to extended organoneodymium nitrate networks

WJ Evans et al.

INORGANIC CHEMISTRY (2004)

Article Chemistry, Inorganic & Nuclear

Synthesis, spectroscopic characterization, and molecular structures of selected Lewis-base adducts of the alkali metal tri(tert-butyl)silylphosphanides

M Westerhausen et al.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE (2003)

Article Chemistry, Multidisciplinary

Synthesis and molecular structure of titanium complexes containing a reduced TEMPO radical

MK Mahanthappa et al.

CHEMICAL COMMUNICATIONS (2002)

Article Chemistry, Inorganic & Nuclear

Novel triphenyltin substituted derivatives of heavier alkaline earth metals

U Englich et al.

JOURNAL OF ORGANOMETALLIC CHEMISTRY (2000)