Journal
INORGANIC CHEMISTRY
Volume 61, Issue 1, Pages 456-463Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.1c03139
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Funding
- Natural Science Foundation of Hainan Province [2019RC005]
- National Natural Science Foundation of China [22061014, 21761010]
- Hainan University start-up fund [KYQD(ZR)1806]
- Opening Project of Key Laboratory of Polyoxometalate and Reticular Material Chemistry of Ministry of Education
- Open Funds of the State Key Laboratory of Rare Earth Resource Utilization [RERU2021020]
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Developing fluorescent materials with multiple and tunable emissions in MOFs can achieve different modes of fluorescence emission for multiple anticounterfeiting purposes. This research provides a new approach for constructing hybrid MOF-based materials with controlled fluorescence properties for emerging anticounterfeiting applications in various fields.
Developing fluorescent materials with multiple and tunable emissions under different conditions is necessary to meet the growing demand for optical anticounterfeiting technology. Different modes of fluorescence emission can be obtained by loading multiple fluorescent components into metal-organic frameworks (MOFs) and modulating the interaction among them for multiple anticounterfeiting purposes. Herein, a Cd-based MOF (HNU-60) was constructed as a host to encapsulate both lanthanide ions and carbon quantum dots. Multiple fluorescence emissions can be achieved by modulation of host-guest and guest-guest interaction, which holds promise for multiple anticounterfeiting applications. This work opens the opportunity to construct the hybrid MOF-based materials with controlled fluorescence properties for emerging anticounterfeiting applications in various fields.
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